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Proton transfers in the Strecker reaction revealed by DFT calculations

The Strecker reaction of acetaldehyde, NH(3), and HCN to afford alanine was studied by DFT calculations for the first time, which involves two reaction stages. In the first reaction stage, the aminonitrile was formed. The rate-determining step is the deprotonation of the NH(3)(+) group in MeCH(OH)-N...

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Bibliografski detalji
Glavni autori: Yamabe, Shinichi, Zeng, Guixiang, Guan, Wei, Sakaki, Shigeyoshi
Format: Artigo
Jezik:Inglês
Izdano: Beilstein-Institut 2014
Teme:
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC4143099/
https://ncbi.nlm.nih.gov/pubmed/25161735
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.10.184
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