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Substrate dependent reaction channels of the Wolff–Kishner reduction reaction: A theoretical study
Wolff–Kishner reduction reactions were investigated by DFT calculations for the first time. B3LYP/6-311+G(d,p) SCRF=(PCM, solvent = 1,2-ethanediol) optimizations were carried out. To investigate the role of the base catalyst, the base-free reaction was examined by the use of acetone, hydrazine (H(2)...
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| Main Authors: | , , , |
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| פורמט: | Artigo |
| שפה: | Inglês |
| יצא לאור: |
Beilstein-Institut
2014
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| נושאים: | |
| גישה מקוונת: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3943666/ https://ncbi.nlm.nih.gov/pubmed/24605145 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.10.21 |
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