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Proton transfers in the Strecker reaction revealed by DFT calculations
The Strecker reaction of acetaldehyde, NH(3), and HCN to afford alanine was studied by DFT calculations for the first time, which involves two reaction stages. In the first reaction stage, the aminonitrile was formed. The rate-determining step is the deprotonation of the NH(3)(+) group in MeCH(OH)-N...
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| Main Authors: | , , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
Beilstein-Institut
2014
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4143099/ https://ncbi.nlm.nih.gov/pubmed/25161735 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.10.184 |
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