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Catalyst–Controlled C–O versus C–N Allylic Functionalization of Terminal Olefins

The divergent synthesis of syn-1, 2-aminoalcohol or syn-1,2-diamine precursors from a common terminal olefin has been accomplished using a combination of palladium(II) catalysis with Lewis acid co-catalysis. Palladium(II)/bis-sulfoxide catalysis with a silver triflate co-catalyst leads for the first...

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Detalhes bibliográficos
Main Authors: Strambeanu, Iulia I., White, M. Christina
Formato: Artigo
Idioma:Inglês
Publicado em: 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4124944/
https://ncbi.nlm.nih.gov/pubmed/23855956
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja405394v
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