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Enantioselective Allylic C–H Oxidation of Terminal Olefins to Isochromans via Pd(II)/Chiral Sulfoxide Catalysis

The enantioselective synthesis of isochroman motifs has been accomplished via Pd(II)-catalyzed allylic C–H oxidation from terminal olefin precursors. Critical to the success of this goal was the development and utilization of a novel chiral aryl sulfoxide-oxazoline (ArSOX) ligand. The allylic C–H ox...

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Gorde:
Xehetasun bibliografikoak
Argitaratua izan da:Angew Chem Int Ed Engl
Egile Nagusiak: Ammann, Stephen E., Liu, Wei, White, M. Christina
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: 2016
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC5729747/
https://ncbi.nlm.nih.gov/pubmed/27376625
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201603576
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