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Catalyst–Controlled C–O versus C–N Allylic Functionalization of Terminal Olefins
The divergent synthesis of syn-1, 2-aminoalcohol or syn-1,2-diamine precursors from a common terminal olefin has been accomplished using a combination of palladium(II) catalysis with Lewis acid co-catalysis. Palladium(II)/bis-sulfoxide catalysis with a silver triflate co-catalyst leads for the first...
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| Hauptverfasser: | , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2013
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4124944/ https://ncbi.nlm.nih.gov/pubmed/23855956 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja405394v |
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