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Catalytic Asymmetric Allylic and Homoallyic Diamination of Terminal Olefins via Formal C-H Activation

[Image: see text] This paper describes a catalytic asymmetric diamination process for terminal olefins at allylic and homoallylic carbons via formal C-H activation using di-t-butyldiaziridinone as nitrogen source with catalyst generated from Pd(2)(dba)(3) and chiral phosphorus amidite ligand. A wide...

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Detalhes bibliográficos
Main Authors: Du, Haifeng, Zhao, Baoguo, Yian, Shi
Formato: Artigo
Idioma:Inglês
Publicado em: 2008
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2776772/
https://ncbi.nlm.nih.gov/pubmed/18549207
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja8027394
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