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Aerobic Linear Allylic C–H Amination: Overcoming Benzoquinone Inhibition
An efficient aerobic linear allylic C—H amination reaction (LAA) is reported under Pd(II)/bis-sulfoxide/Brønsted base catalysis. The reaction operates under preparative, operationally simple conditions (1 equiv. olefin, 1 atm. O(2) or air), with reduced Pd(II)/bis-sulfoxide catalyst loadings while p...
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| 出版年: | J Am Chem Soc |
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| 主要な著者: | , , , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2016
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4831720/ https://ncbi.nlm.nih.gov/pubmed/26730458 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b11294 |
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