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Synthesis of Complex Allylic Esters via C—H Oxidation vs C—C Bond Formation

A highly general, predictably selective C—H oxidation method for the direct, catalytic synthesis of complex allylic esters is introduced. This Pd(II)/sulfoxide-catalyzed method allows a wide range of complex aryl and alkyl carboxylic acids to couple directly with terminal olefins to furnish (E)-ally...

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Autori principali: Vermeulen, Nicolaas A., Delcamp, Jared H., White, M. Christina
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2010
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC3047454/
https://ncbi.nlm.nih.gov/pubmed/20662536
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja104826g
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