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Synthesis of Complex Allylic Esters via C—H Oxidation vs C—C Bond Formation
A highly general, predictably selective C—H oxidation method for the direct, catalytic synthesis of complex allylic esters is introduced. This Pd(II)/sulfoxide-catalyzed method allows a wide range of complex aryl and alkyl carboxylic acids to couple directly with terminal olefins to furnish (E)-ally...
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| Autors principals: | , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2010
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3047454/ https://ncbi.nlm.nih.gov/pubmed/20662536 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja104826g |
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