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Oxidation of Hindered Allylic C–H Bonds with Applications to the Functionalization of Complex Molecules
We report the palladium-catalyzed oxidation of hindered alkenes to form linear allylic esters. The combination of palladium(II) benzoate, 4,5-diazafluoren-9-one, and benzoquinone catalyzes the mild oxidation of terminal alkenes with tert-butyl benzoyl peroxide as an oxidant in the presence of divers...
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| Publicado no: | ACS Catal |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5999342/ https://ncbi.nlm.nih.gov/pubmed/29910970 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.6b03648 |
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