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Remote Oxidation of Aliphatic C—H Bonds in Nitrogen Containing Molecules
Nitrogen heterocycles are ubiquitous in natural products and pharmaceuticals. Herein, we disclose a nitrogen complexation strategy that employs a strong Brønsted acid (HBF(4)) or an azaphilic Lewis acid (BF(3)) to enable remote, non-directed C(sp3)—H oxidations of tertiary (3°), secondary (2°), and...
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| Pubblicato in: | J Am Chem Soc |
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| Autori principali: | , , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2015
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4924472/ https://ncbi.nlm.nih.gov/pubmed/26536374 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b10299 |
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