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Metal-Catalyzed Azidation of Tertiary C–H Bonds Suitable for Late-Stage Functionalization
Some enzymes are able to selectively oxidize unactivated aliphatic C-H bonds to form alcohols; however biological systems do not possess enzymes that are able to catalyze the analogous amination of a C-H bond.(1,2) The absence of such chemistry is limiting because nitrogen-containing groups are foun...
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| Vydáno v: | Nature |
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| Hlavní autoři: | , |
| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
2015
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4311404/ https://ncbi.nlm.nih.gov/pubmed/25631448 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/nature14127 |
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