Chemoselective Amination of Propargylic C(sp(3))–H Bonds via Co(II)-Based Metalloradical Catalysis

Highly chemoselective intramolecular amination of propargylic C(sp(3))–H bonds has been demonstrated for N-bishomopropargylic sulfamoyl azides via Co(II)-based metalloradical catalysis. Supported by D(2h)-symmetric amidoporphyrin ligand 3,5-Di(t)Bu-IbuPhyrin, the Co(II)-catalyzed C–H amination proce...

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Detalhes bibliográficos
Main Authors: Lu, Hongjian, Li, Chaoqun, Jiang, Huiling, Lizardi, Christopher L., Zhang, X. Peter
Formato: Artigo
Idioma:Inglês
Publicado em: 2014
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4119425/
https://ncbi.nlm.nih.gov/pubmed/24840605
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201400557
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