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Catalytic Radical Process for Enantioselective Amination of C(sp(3))-H Bonds
A new catalytic radical system involving Co(II)-based metalloradical catalysis is effective in activating sulfamoyl azides for enantioselective radical 1,6-amination of C(sp(3))-H bonds, affording six-membered chiral heterocyclic sulfamides in high yields with excellent enantioselectivities. The Co(...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6339699/ https://ncbi.nlm.nih.gov/pubmed/30347505 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201808923 |
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