Intramolecular 1,5-C(sp(3))–H radical amination via Co(ii)-based metalloradical catalysis for five-membered cyclic sulfamides

Co(ii)-based metalloradical catalysis (MRC) proves effective for intramolecular 1,5-C–H amination of sulfamoyl azides under neutral and nonoxidative conditions, providing a straightforward approach to access strained 5-membered cyclic sulfamides with nitrogen gas as the only byproduct. The metallora...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Lu, Hongjian, Lang, Kai, Jiang, Huiling, Wojtas, Lukasz, Zhang, X. Peter
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2016
Assuntos:
Chemistry
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5271564/
https://ncbi.nlm.nih.gov/pubmed/28138382
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc02231f
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