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Enantioselective radical process for synthesis of chiral indolines by metalloradical alkylation of diverse C(sp(3))–H bonds
A new C–C bond formation strategy based on enantioselective radical alkylation of C(sp(3))–H bonds via Co(ii)-based metalloradical catalysis has been demonstrated for stereoselective synthesis of chiral indolines. The Co(ii)-based system enables activation of aryldiazomethanes as radical precursors...
Shranjeno v:
| izdano v: | Chem Sci |
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| Main Authors: | , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
Royal Society of Chemistry
2018
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5994879/ https://ncbi.nlm.nih.gov/pubmed/29938039 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc01476k |
| Oznake: |
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