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Metalloradical activation of α-formyldiazoacetates for the catalytic asymmetric radical cyclopropanation of alkenes
For the first time, α-formyldiazoacetates have been successfully applied for the asymmetric cyclopropanation of alkenes via Co(ii)-based metalloradical catalysis. The cobalt(ii) complex of the D (2)-symmetric chiral amidoporphyrin [Co(3,5-Di( t )Bu-ChenPhyrin)] is an effective metalloradical catalys...
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| Publicado no: | Chem Sci |
|---|---|
| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5605771/ https://ncbi.nlm.nih.gov/pubmed/28959396 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc00658f |
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