Asymmetric Radical Cyclopropanation of Alkenes with In Situ-Generated Donor-Substituted Diazo Reagents via Co(II)-Based Metalloradical Catalysis

Donor-substituted diazo reagents, generated in situ from sulfonyl hydrazones in the presence of base, can serve as suitable radical precursors for Co(II)-based metalloradical catalysis (MRC). The cobalt(II) complex of D(2)-symmetric chiral porphyrin [Co(3,5-Di(t)Bu-Xu(2’-Naph)Phyrin)] is an efficien...

Celý popis

Uloženo v:
Podrobná bibliografie
Vydáno v:J Am Chem Soc
Hlavní autoři: Wang, Yong, Wen, Xin, Cui, Xin, Wojtas, Lukasz, Zhang, Peter
Médium: Artigo
Jazyk:Inglês
Vydáno: 2017
Témata:
Article
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5266645/
https://ncbi.nlm.nih.gov/pubmed/28051870
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b11336
Tagy: Přidat tag
Žádné tagy, Buďte první, kdo otaguje tento záznam!

Podobné jednotky