Stereoselective radical C–H alkylation with acceptor/acceptor-substituted diazo reagents via Co(ii)-based metalloradical catalysis

Co(ii)-based metalloradical catalysis has, for the first time, been successfully applied for asymmetric intramolecular C–H alkylation of acceptor/acceptor-substituted diazo reagents. Through the design and synthesis of a new D (2)-symmetric chiral amidoporphyrin as the supporting ligand, the Co(ii)-...

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Veröffentlicht in:Chem Sci
Hauptverfasser: Cui, Xin, Xu, Xue, Jin, Li-Mei, Wojtas, Lukasz, Zhang, X. Peter
Format: Artigo
Sprache:Inglês
Veröffentlicht: Royal Society of Chemistry 2015
Schlagworte:
Chemistry
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4324598/
https://ncbi.nlm.nih.gov/pubmed/25685314
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc02610a
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