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Stereoselective radical C–H alkylation with acceptor/acceptor-substituted diazo reagents via Co(ii)-based metalloradical catalysis
Co(ii)-based metalloradical catalysis has, for the first time, been successfully applied for asymmetric intramolecular C–H alkylation of acceptor/acceptor-substituted diazo reagents. Through the design and synthesis of a new D (2)-symmetric chiral amidoporphyrin as the supporting ligand, the Co(ii)-...
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| Pubblicato in: | Chem Sci |
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| Autori principali: | , , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
Royal Society of Chemistry
2015
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4324598/ https://ncbi.nlm.nih.gov/pubmed/25685314 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc02610a |
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