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Asymmetric Radical Cyclopropanation of Alkenes with In Situ-Generated Donor-Substituted Diazo Reagents via Co(II)-Based Metalloradical Catalysis
Donor-substituted diazo reagents, generated in situ from sulfonyl hydrazones in the presence of base, can serve as suitable radical precursors for Co(II)-based metalloradical catalysis (MRC). The cobalt(II) complex of D(2)-symmetric chiral porphyrin [Co(3,5-Di(t)Bu-Xu(2’-Naph)Phyrin)] is an efficien...
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| 出版年: | J Am Chem Soc |
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| 主要な著者: | , , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2017
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5266645/ https://ncbi.nlm.nih.gov/pubmed/28051870 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b11336 |
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