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Regioselective Synthesis of Multisubstituted Furans via Metalloradical Cyclization of Alkynes with α-Diazocarbonyls: Construction of Functionalized α-Oligofurans
Co(III)-carbene radicals generated from activation of α-diazocarbonyls by Co(II) porphyrin complexes have been shown to undergo a new type of tandem radical addition reaction with alkynes to construct 5-membered furan structures. Cobalt(II) complex of 3,5-Di(t)Bu-IbuPhyrin, [Co(P1)], has proven to b...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3531582/ https://ncbi.nlm.nih.gov/pubmed/23205846 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja309446n |
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