Regioselective Synthesis of Multisubstituted Furans via Metalloradical Cyclization of Alkynes with α-Diazocarbonyls: Construction of Functionalized α-Oligofurans

Co(III)-carbene radicals generated from activation of α-diazocarbonyls by Co(II) porphyrin complexes have been shown to undergo a new type of tandem radical addition reaction with alkynes to construct 5-membered furan structures. Cobalt(II) complex of 3,5-Di(t)Bu-IbuPhyrin, [Co(P1)], has proven to b...

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Main Authors: Cui, Xin, Xu, Xue, Wojtas, Lukasz, Kim, Martin M., Zhang, X. Peter
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3531582/
https://ncbi.nlm.nih.gov/pubmed/23205846
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja309446n
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