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Chemoselective Amination of Propargylic C(sp(3))–H Bonds via Co(II)-Based Metalloradical Catalysis
Highly chemoselective intramolecular amination of propargylic C(sp(3))–H bonds has been demonstrated for N-bishomopropargylic sulfamoyl azides via Co(II)-based metalloradical catalysis. Supported by D(2h)-symmetric amidoporphyrin ligand 3,5-Di(t)Bu-IbuPhyrin, the Co(II)-catalyzed C–H amination proce...
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| Huvudupphovsmän: | , , , , |
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| Materialtyp: | Artigo |
| Språk: | Inglês |
| Publicerad: |
2014
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| Ämnen: | |
| Länkar: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4119425/ https://ncbi.nlm.nih.gov/pubmed/24840605 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201400557 |
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