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Selective Radical Amination of Aldehydic C(sp(2))–H Bonds with Fluoroaryl Azides via Co(II)-Based Metalloradical Catalysis: Synthesis of N-Fluoroaryl Amides from Aldehydes under Neutral and Nonoxidative Conditions
The Co(II) complex of the D(2h)-symmetric amidoporphyrin 3,5-Di(t)Bu-IbuPhyrin, [Co(P1)], has proven to be an effective metalloradical catalyst for intermolecular amination of C(sp(2))–H bonds of aldehydes with fluoroaryl azides. The [Co(P1)]-catalyzed process can employ aldehydes as the limiting re...
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| Main Authors: | , , , , , , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2014
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4111259/ https://ncbi.nlm.nih.gov/pubmed/25071929 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C4SC00697F |
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