Selective Radical Amination of Aldehydic C(sp(2))–H Bonds with Fluoroaryl Azides via Co(II)-Based Metalloradical Catalysis: Synthesis of N-Fluoroaryl Amides from Aldehydes under Neutral and Nonoxidative Conditions

The Co(II) complex of the D(2h)-symmetric amidoporphyrin 3,5-Di(t)Bu-IbuPhyrin, [Co(P1)], has proven to be an effective metalloradical catalyst for intermolecular amination of C(sp(2))–H bonds of aldehydes with fluoroaryl azides. The [Co(P1)]-catalyzed process can employ aldehydes as the limiting re...

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Main Authors: Jin, Li-Mei, Lu, Hongjian, Cui, Yuan, Lizardi, Christopher L., Arzua, Thiago N., Wojtas, Lukasz, Cui, Xin, Zhang, X. Peter
Formato: Artigo
Idioma:Inglês
Publicado em: 2014
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4111259/
https://ncbi.nlm.nih.gov/pubmed/25071929
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C4SC00697F
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