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Total Synthesis of Kingianin A
[Image: see text] A 12-step synthesis of kingianin A, an inhibitor of the antiapoptotic protein Bcl-xL, is based on a radical cation Diels Alder reaction (RCDA). This approach is thought to be biomimetic. The use of a tether in the key RCDA step controls the regiochemistry of the cycloaddition, lead...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4024395/ https://ncbi.nlm.nih.gov/pubmed/23273168 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol303388k |
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