Mechanism, Reactivity, and Selectivity in Palladium-Catalyzed Redox-Relay Heck Arylations of Alkenyl Alcohols

[Image: see text] The enantioselective Pd-catalyzed redox-relay Heck arylation of acyclic alkenyl alcohols allows access to various useful chiral building blocks from simple olefinic substrates. Mechanistically, after the initial migratory insertion, a succession of β-hydride elimination and migrato...

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Main Authors: Xu, Liping, Hilton, Margaret J., Zhang, Xinhao, Norrby, Per-Ola, Wu, Yun-Dong, Sigman, Matthew S., Wiest, Olaf
Format: Artigo
Jezik:Inglês
Izdano: American Chemical Society 2014
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC3985895/
https://ncbi.nlm.nih.gov/pubmed/24410393
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja4109616
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