Relative reactivity of alkenyl alcohols in the palladium-catalyzed redox-relay Heck reaction

The relative rates of alkenyl alcohols in the Pd-catalyzed redox-relay Heck reaction were measured in order to examine the effect of their steric and electronic properties on the rate-determining step. Competition experiments between an allylic alkenyl alcohol and two substrates with differing chain...

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Veröffentlicht in:Tetrahedron
Hauptverfasser: Hilton, Margaret J., Cheng, Bin, Buckley, Benjamin R., Xu, Liping, Wiest, Olaf, Sigman, Matthew S.
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2015
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Article
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4573459/
https://ncbi.nlm.nih.gov/pubmed/26392640
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2015.05.020
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