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Palladium-catalyzed enantioselective Heck alkenylation of trisubstituted allylic alkenols: a redox-relay strategy to construct vicinal stereocenters

An enantioselective, redox-relay Heck alkenylation of trisubstituted allylic alkenol substrates has been developed. This process enables the construction of vicinal stereocenters in high diastereo- and enantioselectivity and allows the formation of enolizable α-carbonyl methyl-substituted stereocent...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Zhang, Chun, Tutkowski, Brandon, DeLuca, Ryan J., Joyce, Leo A., Wiest, Olaf, Sigman, Matthew S.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5395252/
https://ncbi.nlm.nih.gov/pubmed/28435657
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc04585e
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