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Concise Enantiospecific Total Synthesis of Tubingensin A
[Image: see text] We report the enantiospecific total synthesis of (+)-tubingensin A. Our synthesis features an aryne cyclization to efficiently introduce the vicinal quaternary stereocenters of the natural product and proceeds in only nine steps (longest linear sequence) from known compounds.
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Chemical
Society
2014
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3985696/ https://ncbi.nlm.nih.gov/pubmed/24524351 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja501142e |
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