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Concise Enantiospecific Total Synthesis of Tubingensin A

[Image: see text] We report the enantiospecific total synthesis of (+)-tubingensin A. Our synthesis features an aryne cyclization to efficiently introduce the vicinal quaternary stereocenters of the natural product and proceeds in only nine steps (longest linear sequence) from known compounds.

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Autors principals: Goetz, Adam E., Silberstein, Amanda L., Corsello, Michael A., Garg, Neil K.
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2014
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3985696/
https://ncbi.nlm.nih.gov/pubmed/24524351
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja501142e
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