Loading...
A Concise Total Synthesis of (±)-Vibralactone
Disclosed is a five-step synthesis of (±)-vibralactone, a biologically active terpenoid natural product. A key photochemical valence isomerization of 3-prenyl-pyran-2-one forges both the all-carbon quaternary stereocenter and the β-lactone at an early stage. Cyclopropanation of the resulting bicycli...
Saved in:
| Published in: | Angew Chem Int Ed Engl |
|---|---|
| Main Authors: | , , , |
| Format: | Artigo |
| Language: | Inglês |
| Published: |
2019
|
| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6351154/ https://ncbi.nlm.nih.gov/pubmed/30548983 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201812711 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|