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A Concise Total Synthesis of (±)-Vibralactone
Disclosed is a five-step synthesis of (±)-vibralactone, a biologically active terpenoid natural product. A key photochemical valence isomerization of 3-prenyl-pyran-2-one forges both the all-carbon quaternary stereocenter and the β-lactone at an early stage. Cyclopropanation of the resulting bicycli...
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| Foilsithe in: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , |
| Formáid: | Artigo |
| Teanga: | Inglês |
| Foilsithe: |
2019
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| Ábhair: | |
| Rochtain Ar Líne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6351154/ https://ncbi.nlm.nih.gov/pubmed/30548983 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201812711 |
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