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An Efficient Approach to Mechanically Planar Chiral Rotaxanes

[Image: see text] We describe the first method for production of mechanically planar chiral rotaxanes in excellent enantiopurity without the use of chiral separation techniques and, for the first time, unambiguously assign the absolute stereochemistry of the products. This proof-of-concept study, wh...

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Autori principali: Bordoli, Robert J., Goldup, Stephen M.
Natura: Artigo
Lingua:Inglês
Pubblicazione: American Chemical Society 2014
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC3977585/
https://ncbi.nlm.nih.gov/pubmed/24559064
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja412715m
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