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Vibrational circular dichroism spectroscopy for probing the expression of chirality in mechanically planar chiral rotaxanes

Mechanically interlocked molecules can exhibit molecular chirality that arises due to the mechanical bond rather than covalent stereogenic units. Developing applications of such systems is made challenging by the absence of techniques for assigning the absolute configuration of products and methods...

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Détails bibliographiques
Publié dans:Chem Sci
Auteurs principaux: Koenis, Mark A. J., Chibueze, C. S., Jinks, M. A., Nicu, Valentin P., Visscher, Lucas, Goldup, S. M., Buma, Wybren J.
Format: Artigo
Langue:Inglês
Publié: The Royal Society of Chemistry 2020
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC8163398/
https://ncbi.nlm.nih.gov/pubmed/34123106
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc02485f
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