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Vibrational circular dichroism spectroscopy for probing the expression of chirality in mechanically planar chiral rotaxanes

Mechanically interlocked molecules can exhibit molecular chirality that arises due to the mechanical bond rather than covalent stereogenic units. Developing applications of such systems is made challenging by the absence of techniques for assigning the absolute configuration of products and methods...

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Vydáno v:Chem Sci
Hlavní autoři: Koenis, Mark A. J., Chibueze, C. S., Jinks, M. A., Nicu, Valentin P., Visscher, Lucas, Goldup, S. M., Buma, Wybren J.
Médium: Artigo
Jazyk:Inglês
Vydáno: The Royal Society of Chemistry 2020
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC8163398/
https://ncbi.nlm.nih.gov/pubmed/34123106
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc02485f
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