Stereoselective Synthesis of Mechanically Planar Chiral Rotaxanes

Chiral interlocked molecules in which the mechanical bond provides the sole stereogenic unit are typically produced with no control over the mechanical stereochemistry. Here we report a stereoselective approach to mechanically planar chiral rotaxanes in up to 98:2 d.r. using a readily available α‐am...

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Dettagli Bibliografici
Pubblicato in:Angew Chem Int Ed Engl
Autori principali: Jinks, Michael A., de Juan, Alberto, Denis, Mathieu, Fletcher, Catherine J., Galli, Marzia, Jamieson, Ellen M. G., Modicom, Florian, Zhang, Zhihui, Goldup, Stephen M.
Natura: Artigo
Lingua:Inglês
Pubblicazione: John Wiley and Sons Inc. 2018
Soggetti:
Communications
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6220991/
https://ncbi.nlm.nih.gov/pubmed/30253008
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201808990
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