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A chiral interlocking auxiliary strategy for the synthesis of mechanically planar chiral rotaxanes

Rotaxanes can display molecular chirality solely due to the mechanical bond between the axle and encircling macrocycle without the presence of covalent stereogenic units. However, the synthesis of such molecules remains challenging. We have discovered a combination of reaction partners that function...

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Библиографические подробности
Опубликовано в: :Nat Chem
Главные авторы: de Juan, Alberto, Lozano, David, Heard, Andrew W., Jinks, Michael A., Suarez, Jorge Meijide, Tizzard, Graham J., Goldup, Stephen M.
Формат: Artigo
Язык:Inglês
Опубликовано: 2022
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Online-ссылка:https://ncbi.nlm.nih.gov/pmc/articles/PMC7612332/
https://ncbi.nlm.nih.gov/pubmed/34845345
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41557-021-00825-9
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