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A chiral interlocking auxiliary strategy for the synthesis of mechanically planar chiral rotaxanes

Rotaxanes can display molecular chirality solely due to the mechanical bond between the axle and encircling macrocycle without the presence of covalent stereogenic units. However, the synthesis of such molecules remains challenging. We have discovered a combination of reaction partners that function...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Veröffentlicht in:Nat Chem
Hauptverfasser: de Juan, Alberto, Lozano, David, Heard, Andrew W., Jinks, Michael A., Suarez, Jorge Meijide, Tizzard, Graham J., Goldup, Stephen M.
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2022
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7612332/
https://ncbi.nlm.nih.gov/pubmed/34845345
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41557-021-00825-9
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