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A chiral interlocking auxiliary strategy for the synthesis of mechanically planar chiral rotaxanes
Rotaxanes can display molecular chirality solely due to the mechanical bond between the axle and encircling macrocycle without the presence of covalent stereogenic units. However, the synthesis of such molecules remains challenging. We have discovered a combination of reaction partners that function...
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| Veröffentlicht in: | Nat Chem |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2022
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7612332/ https://ncbi.nlm.nih.gov/pubmed/34845345 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41557-021-00825-9 |
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