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Mechanically axially chiral catenanes and noncanonical mechanically axially chiral rotaxanes

Chirality typically arises in molecules because of a rigidly chiral arrangement of covalently bonded atoms. Less generally appreciated is that chirality can arise when molecules are threaded through one another to create a mechanical bond. For example, when two macrocycles with chemically distinct f...

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Pubblicato in:Nat Chem
Autori principali: Maynard, John R.J., Gallagher, Peter, Lozano, David, Butler, Patrick, Goldup, Stephen M.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2022
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC7613450/
https://ncbi.nlm.nih.gov/pubmed/35760959
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41557-022-00973-6
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