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Catalytic asymmetric addition of diorganozinc reagents to N-phosphinoylalkylimines
The synthesis of α-chiral amines bearing two alkyl groups has been hampered by the accessibility and stability of the alkylimine precursor. Herein, we report an efficient strategy to generate the alkyl-substituted imine in situ that is compatible with the Me-DuPHOS monoxide·Cu(I) catalyzed addition...
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| Publicado en: | Proc Natl Acad Sci U S A |
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| Autores principales: | , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
National Academy of Sciences
2004
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC397394/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/15064400/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.0307096101 |
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