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Catalytic asymmetric addition of diorganozinc reagents to N-phosphinoylalkylimines
The synthesis of α-chiral amines bearing two alkyl groups has been hampered by the accessibility and stability of the alkylimine precursor. Herein, we report an efficient strategy to generate the alkyl-substituted imine in situ that is compatible with the Me-DuPHOS monoxide·Cu(I) catalyzed addition...
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| Autors principals: | , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
National Academy of Sciences
2004
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC397394/ https://ncbi.nlm.nih.gov/pubmed/15064400 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0307096101 |
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