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Copper-catalyzed asymmetric conjugate addition of Grignard reagents to cyclic enones
It is no longer necessary to use dialkylzinc reagents to obtain enantioselectivities >95% in the copper-catalyzed asymmetric conjugate addition of organometallic compounds to cyclic enones. We now report how this can be accomplished by using inexpensive and readily available Grignard reagents. Sc...
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| Gepubliceerd in: | Proc Natl Acad Sci U S A |
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| Hoofdauteurs: | , , , , |
| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
National Academy of Sciences
2004
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| Onderwerpen: | |
| Online toegang: | https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC395995/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/15075388/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.0308008101 |
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