Copper-catalyzed asymmetric conjugate addition of Grignard reagents to cyclic enones

It is no longer necessary to use dialkylzinc reagents to obtain enantioselectivities >95% in the copper-catalyzed asymmetric conjugate addition of organometallic compounds to cyclic enones. We now report how this can be accomplished by using inexpensive and readily available Grignard reagents. Sc...

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Detaylı Bibliyografya
Yayımlandı:Proc Natl Acad Sci U S A
Asıl Yazarlar: Feringa, Ben L., Badorrey, Ramón, Peña, Diego, Harutyunyan, Syuzanna R., Minnaard, Adriaan J.
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: National Academy of Sciences 2004
Konular:
Asymmetric Catalysis Special Feature Part II
Online Erişim:https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC395995/
https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/15075388/
https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.0308008101
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