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Copper-catalyzed asymmetric conjugate addition of Grignard reagents to cyclic enones
It is no longer necessary to use dialkylzinc reagents to obtain enantioselectivities >95% in the copper-catalyzed asymmetric conjugate addition of organometallic compounds to cyclic enones. We now report how this can be accomplished by using inexpensive and readily available Grignard reagents. Sc...
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| Autors principals: | , , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
National Academy of Sciences
2004
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC395995/ https://ncbi.nlm.nih.gov/pubmed/15075388 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0308008101 |
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