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Catalytic asymmetric addition of diphenylzinc to cyclic α,β-unsaturated ketones
We have examined the use of our bis(sulfonamide) diol ligand (1) in the asymmetric addition of phenyl groups to cyclic α,β-unsaturated ketones. Good to excellent enantioselectivities have been obtained with cyclic enones bearing alkyl substituents in the 2 position (71–97% enantiomeric excess). Furt...
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| Publicado en: | Proc Natl Acad Sci U S A |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
National Academy of Sciences
2004
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC397398/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/15067130/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.0307119101 |
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