Asymmetric hydrogenation of α,β-unsaturated phosphonates with Rh-BisP* and Rh-MiniPHOS catalysts: Scope and mechanism of the reaction

Optically active 1,2-bis(alkylmethylphosphino)ethanes and bis(alkylmethylphosphino)methanes are unique diphosphine ligands combining the simple molecular structure and P-stereogenic asymmetric environment. This work shows that these ligands exhibit excellent enantioselectivity in rhodium-catalyzed a...

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Publicado en:Proc Natl Acad Sci U S A
Autores principales: Gridnev, Ilya D., Yasutake, Masaya, Imamoto, Tsuneo, Beletskaya, Irina P.
Formato: Artigo
Lenguaje:Inglês
Publicado: National Academy of Sciences 2004
Materias:
Asymmetric Catalysis Special Feature Part I
Acceso en línea:https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC397390/
https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/15024119/
https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.0306993101
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