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Asymmetric autocatalysis: Novel structures, novel mechanism?

The amplifying asymmetric autocatalysis discovered by Soai and coworkers in 1995 does not fit easily into the extensively investigated framework of organozinc alkylation of aldehydes. In that case the catalyst is a monomeric Zn chelate that functions as both Lewis acid and Lewis base, permitting the...

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Autores principales: Gridnev, Ilya D., Brown, John M.
Formato: Artigo
Lenguaje:Inglês
Publicado: National Academy of Sciences 2004
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC395975/
https://ncbi.nlm.nih.gov/pubmed/15060283
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0308178101
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