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Asymmetric autocatalysis: Novel structures, novel mechanism?

The amplifying asymmetric autocatalysis discovered by Soai and coworkers in 1995 does not fit easily into the extensively investigated framework of organozinc alkylation of aldehydes. In that case the catalyst is a monomeric Zn chelate that functions as both Lewis acid and Lewis base, permitting the...

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Bibliographic Details
Main Authors: Gridnev, Ilya D., Brown, John M.
Format: Artigo
Language:Inglês
Published: National Academy of Sciences 2004
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC395975/
https://ncbi.nlm.nih.gov/pubmed/15060283
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0308178101
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