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Asymmetric hydrogenation of α,β-unsaturated phosphonates with Rh-BisP* and Rh-MiniPHOS catalysts: Scope and mechanism of the reaction

Optically active 1,2-bis(alkylmethylphosphino)ethanes and bis(alkylmethylphosphino)methanes are unique diphosphine ligands combining the simple molecular structure and P-stereogenic asymmetric environment. This work shows that these ligands exhibit excellent enantioselectivity in rhodium-catalyzed a...

詳細記述

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書誌詳細
主要な著者: Gridnev, Ilya D., Yasutake, Masaya, Imamoto, Tsuneo, Beletskaya, Irina P.
フォーマット: Artigo
言語:Inglês
出版事項: National Academy of Sciences 2004
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC397390/
https://ncbi.nlm.nih.gov/pubmed/15024119
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0306993101
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