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Cysteine Pseudoprolines for Thiol Protection and Peptide Macrocyclization Enhancement in Fmoc-Based Solid-Phase Peptide Synthesis

[Image: see text] Contrary to other studies, here we describe cysteine (Cys) pseudoproline-containing peptides with short deprotection times in TFA. The deprotection times fell in the same range as other protecting groups commonly used in SPPS (e.g., 1–3 h). Moreover, when using Cys pseudoprolines a...

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Detalhes bibliográficos
Main Authors: Postma, Tobias M., Albericio, Fernando
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2014
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3971734/
https://ncbi.nlm.nih.gov/pubmed/24617568
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol5004725
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