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Rh(2)(R-TPCP)(4)-Catalyzed Enantioselective [3+2]-Cycloaddition between Nitrones and Vinyldiazoacetates
Rhodium-catalyzed reaction of vinyldiazoacetates with nitrones results in a formal [3+2]-cycloaddition to generate 2,5-dihydroisoxazoles with high levels of asymmetric induction. The cascade reaction begins with a vinylogous addition event, followed by an iminium addition ring-closure/hydride migrat...
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| 主要な著者: | , |
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| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2013
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3952076/ https://ncbi.nlm.nih.gov/pubmed/24025195 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja4069003 |
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