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H(2)O(2)-dependent substrate oxidation by an engineered diiron site in a bacterial hemerythrin
The O(2)-binding carboxylate-bridged diiron site in DcrH-Hr was engineered in an effort to perform the H(2)O(2)-dependent oxidation of external substrates. A His residue was introduced near the diiron site in place of a conserved residue, Ile119. The I119H variant promotes the oxidation of guaiacol...
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| Главные авторы: | , , , , , , , |
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| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
Royal Society of Chemistry
2014
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3947700/ https://ncbi.nlm.nih.gov/pubmed/24400317 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c3cc48108e |
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