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Enantioselective Total Synthesis of (−)-Minovincine in Nine Chemical Steps: An Approach to Ketone Activation in Cascade Catalysis
[Image: see text] MORE CYCLING–FEWER STEPS: The first enantioselective total synthesis of (−)-minovincine has been accomplished in nine chemical steps and 13% overall yield. A novel, one-step Diels–Alder/β-elimination/conjugate addition organocascade sequence allowed rapid access to the central tetr...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3934209/ https://ncbi.nlm.nih.gov/pubmed/24000234 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201305171 |
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