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Enantioselective Polyene Cyclization via Organo-SOMO Catalysis

The first organocatalytic enantioselective radical polycyclization has been accomplished using singly occupied molecular orbital (SOMO) catalysis. The presented strategy relies on a selective single-electron oxidation of chiral enamines formed by condensation of polyenals with an imidazolidinone cat...

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Bibliografiske detaljer
Main Authors: Rendler, Sebastian, MacMillan, David W. C.
Format: Artigo
Sprog:Inglês
Udgivet: 2010
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2880463/
https://ncbi.nlm.nih.gov/pubmed/20334384
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja100185p
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