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Enantioselective Polyene Cyclization via Organo-SOMO Catalysis
The first organocatalytic enantioselective radical polycyclization has been accomplished using singly occupied molecular orbital (SOMO) catalysis. The presented strategy relies on a selective single-electron oxidation of chiral enamines formed by condensation of polyenals with an imidazolidinone cat...
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| Auteurs principaux: | , |
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| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2010
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2880463/ https://ncbi.nlm.nih.gov/pubmed/20334384 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja100185p |
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